QUADRUPOLE TECHNOLOGY
FROM CLASSICS TO MODERNS
W. Paul, Reviews of Modern Physics, 62, 3, 1990
ELLIPTICAL QUADRUPOLE MASS FILTER
REINVENTING THE WHEEL
Conventional QMF
Elliptical QMF
Here we introduce a new 2D electrode structure with an elliptic geometry. This means that it has different distances from the electrode center to the electrodes along coordinate axes. In contrast to a conventional mass filter with a characteristic inscribed circle, the modified electrode system can be characterized by an inscribed ellipse.
Note, that this new structure also produces quadrupole field since the hyperbolic electrodes have common asymptotes.
As a result of such transformation, the mass filter demonstrates an increased ion transmission and increased mass range.
TRIPOLE MASS FILTER
This structure consists of three hyperbolic electrodes and one grounded V-shaped electrode. It resembles the quadrupole mass filter, but a V-shaped electrode is used instead of one hyperbolic electrode. Operational principles of this analyzer are similar to the monopole mass filter, as it also utilizes a one-dimensional ion sorting. This new filter represents an intermediate structure between the monopole and quadrupole mass filters. It combines advantages of both mass spectrometers and does not suffer from their disadvantages: the monopole mass filter usually has lower sensitivity than a quadrupole mass filter, whereas the latter shows a better mass peak shape; the quadrupole mass filter requires high mechanical accuracy and high stability of DC and RF voltages.
3D ELLIPTICAL ION TRAPS
Electrode system transformation
Axially symmetrical ion trap
Elliptical ion trap
FABRICATION TECHNOLOGY
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