QUADRUPOLE TECHNOLOGY

FROM CLASSICS TO MODERNS

W. Paul, Reviews of Modern Physics, 62, 3, 1990

 

ELLIPTICAL QUADRUPOLE MASS FILTER

REINVENTING THE WHEEL

Conventional QMF

Elliptical QMF

Here we introduce a new 2D electrode structure  with an elliptic geometry.  This means that it has different distances from the electrode center to the electrodes along coordinate axes.  In contrast to a conventional mass filter with a characteristic inscribed circle, the modified electrode system can be characterized by an inscribed ellipse.

Note, that this new structure also produces quadrupole field since the hyperbolic electrodes have common asymptotes.

As a result of such transformation, the mass filter  demonstrates an increased ion transmission and  increased mass range.

TRIPOLE MASS FILTER

 This structure consists of three hyperbolic electrodes and one grounded V-shaped electrode. It resembles the quadrupole mass filter, but a V-shaped electrode is used instead of one hyperbolic electrode. Operational principles of this analyzer are similar to the monopole mass filter, as it also utilizes a one-dimensional ion sorting. This new filter represents an intermediate structure between the monopole and quadrupole  mass filters. It combines advantages of both mass spectrometers and does not suffer from their disadvantages: the monopole mass filter usually has lower sensitivity than a quadrupole mass filter, whereas the latter shows a better mass peak shape; the quadrupole mass filter requires high mechanical accuracy and high stability of DC and RF voltages.

3D ELLIPTICAL ION TRAPS

Electrode system transformation

Axially symmetrical ion trap

Elliptical ion trap

FABRICATION TECHNOLOGY

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